BM590_B0013 PWY-6012 acyl carrier protein metabolism I BM590_B0013 PWY-6012-1 acyl carrier protein metabolism II (mammalian) BM590_B0014 PWY-5901 2,3-dihydroxybenzoate biosynthesis BM590_B0015 PWY-5901 2,3-dihydroxybenzoate biosynthesis BM590_B0017 PWY-5791 1,4-dihydroxy-2-naphthoate biosynthesis II (plants) BM590_B0017 PWY-5837 1,4-dihydroxy-2-naphthoate biosynthesis I BM590_B0017 PWY-5901 2,3-dihydroxybenzoate biosynthesis BM590_B0017 PWY-6406 salicylate biosynthesis I BM590_B0037 PWY-6163 chorismate biosynthesis from 3-dehydroquinate BM590_B0073 PWY-3801 sucrose degradation II (sucrose synthase) BM590_B0073 PWY-6527 stachyose degradation BM590_B0073 PWY-6981 chitin biosynthesis BM590_B0073 PWY-7238 sucrose biosynthesis II BM590_B0073 PWY-7343 UDP-glucose biosynthesis BM590_B0083 PWY-5958 acridone alkaloid biosynthesis BM590_B0083 PWY-6543 4-aminobenzoate biosynthesis BM590_B0083 PWY-6660 2-heptyl-3-hydroxy-4(1H)-quinolone biosynthesis BM590_B0083 PWY-6661 4-hydroxy-2(1H)-quinolone biosynthesis BM590_B0083 PWY-6722 candicidin biosynthesis BM590_B0087 PWY-2221 Entner-Doudoroff pathway III (semi-phosphorylative) BM590_B0087 PWY-6507 4-deoxy-L-threo-hex-4-enopyranuronate degradation BM590_B0087 PWY-7242 D-fructuronate degradation BM590_B0087 PWY-7310 D-glucosaminate degradation BM590_B0099 PWY-5921 glutaminyl-tRNAgln biosynthesis via transamidation BM590_B0131 PWY-7219 adenosine ribonucleotides de novo biosynthesis BM590_B0175 PWY-6386 UDP-N-acetylmuramoyl-pentapeptide biosynthesis II (lysine-containing) BM590_B0175 PWY-6387 UDP-N-acetylmuramoyl-pentapeptide biosynthesis I (meso-diaminopimelate containing) BM590_B0176 PWY-6386 UDP-N-acetylmuramoyl-pentapeptide biosynthesis II (lysine-containing) BM590_B0176 PWY-6387 UDP-N-acetylmuramoyl-pentapeptide biosynthesis I (meso-diaminopimelate containing) BM590_B0188 PWY-5392 reductive TCA cycle II BM590_B0188 PWY-561 superpathway of glyoxylate cycle and fatty acid degradation BM590_B0188 PWY-5690 TCA cycle II (plants and fungi) BM590_B0188 PWY-5913 TCA cycle VI (obligate autotrophs) BM590_B0188 PWY-6728 methylaspartate cycle BM590_B0188 PWY-6969 TCA cycle V (2-oxoglutarate:ferredoxin oxidoreductase) BM590_B0188 PWY-7254 TCA cycle VII (acetate-producers) BM590_B0188 PWY-7384 anaerobic energy metabolism (invertebrates, mitochondrial) BM590_B0194 PWY-5523 5,6-dimethylbenzimidazole biosynthesis BM590_B0194 PWY-6167 flavin biosynthesis II (archaea) BM590_B0194 PWY-6168 flavin biosynthesis III (fungi) BM590_B0217 PWY-1361 benzoyl-CoA degradation I (aerobic) BM590_B0217 PWY-5109 2-methylbutanoate biosynthesis BM590_B0217 PWY-5136 fatty acid β-oxidation II (peroxisome) BM590_B0217 PWY-5138 unsaturated, even numbered fatty acid β-oxidation BM590_B0217 PWY-5177 glutaryl-CoA degradation BM590_B0217 PWY-5789 3-hydroxypropanoate/4-hydroxybutanate cycle BM590_B0217 PWY-6435 4-hydroxybenzoate biosynthesis V BM590_B0217 PWY-6583 pyruvate fermentation to butanol I BM590_B0217 PWY-6863 pyruvate fermentation to hexanol BM590_B0217 PWY-6883 pyruvate fermentation to butanol II BM590_B0217 PWY-6944 androstenedione degradation BM590_B0217 PWY-6945 cholesterol degradation to androstenedione I (cholesterol oxidase) BM590_B0217 PWY-6946 cholesterol degradation to androstenedione II (cholesterol dehydrogenase) BM590_B0217 PWY-7007 methyl ketone biosynthesis BM590_B0217 PWY-7046 4-coumarate degradation (anaerobic) BM590_B0217 PWY-7094 fatty acid salvage BM590_B0217 PWY-7216 (R)- and (S)-3-hydroxybutanoate biosynthesis BM590_B0217 PWY-735 jasmonic acid biosynthesis BM590_B0217 PWY-7401 crotonate fermentation (to acetate and cyclohexane carboxylate) BM590_B0240 PWY-3781 aerobic respiration I (cytochrome c) BM590_B0240 PWY-4521 arsenite oxidation I (respiratory) BM590_B0240 PWY-6692 Fe(II) oxidation BM590_B0240 PWY-7279 aerobic respiration II (cytochrome c) (yeast) BM590_B0251 PWY-6523 nitrite-dependent anaerobic methane oxidation BM590_B0251 PWY-6748 nitrate reduction VII (denitrification) BM590_B0251 PWY-7084 nitrifier denitrification BM590_B0260 PWY-4261 glycerol degradation I BM590_B0268 PWY-6748 nitrate reduction VII (denitrification) BM590_B0268 PWY-7084 nitrifier denitrification BM590_B0308 PWY-6545 pyrimidine deoxyribonucleotides de novo biosynthesis III BM590_B0308 PWY-7184 pyrimidine deoxyribonucleotides de novo biosynthesis I BM590_B0308 PWY-7198 pyrimidine deoxyribonucleotides de novo biosynthesis IV BM590_B0308 PWY-7210 pyrimidine deoxyribonucleotides biosynthesis from CTP BM590_B0308 PWY-7220 adenosine deoxyribonucleotides de novo biosynthesis II BM590_B0308 PWY-7222 guanosine deoxyribonucleotides de novo biosynthesis II BM590_B0308 PWY-7226 guanosine deoxyribonucleotides de novo biosynthesis I BM590_B0308 PWY-7227 adenosine deoxyribonucleotides de novo biosynthesis BM590_B0309 PWY-6545 pyrimidine deoxyribonucleotides de novo biosynthesis III BM590_B0309 PWY-7184 pyrimidine deoxyribonucleotides de novo biosynthesis I BM590_B0309 PWY-7198 pyrimidine deoxyribonucleotides de novo biosynthesis IV BM590_B0309 PWY-7210 pyrimidine deoxyribonucleotides biosynthesis from CTP BM590_B0309 PWY-7220 adenosine deoxyribonucleotides de novo biosynthesis II BM590_B0309 PWY-7222 guanosine deoxyribonucleotides de novo biosynthesis II BM590_B0309 PWY-7226 guanosine deoxyribonucleotides de novo biosynthesis I BM590_B0309 PWY-7227 adenosine deoxyribonucleotides de novo biosynthesis BM590_B0326 PWY-4321 L-glutamate degradation IV BM590_B0336 PWY-5659 GDP-mannose biosynthesis BM590_B0336 PWY-6073 alginate biosynthesis I (algal) BM590_B0336 PWY-6082 alginate biosynthesis II (bacterial) BM590_B0336 PWY-882 L-ascorbate biosynthesis I (L-galactose pathway) BM590_B0337 PWY-6749 CMP-legionaminate biosynthesis I BM590_B0338 PWY-5154 L-arginine biosynthesis III (via N-acetyl-L-citrulline) BM590_B0340 PWY-5695 urate biosynthesis/inosine 5'-phosphate degradation BM590_B0340 PWY-6596 adenosine nucleotides degradation I BM590_B0340 PWY-7221 guanosine ribonucleotides de novo biosynthesis BM590_B0343 PWY-5506 methanol oxidation to formaldehyde IV BM590_B0350 PWY-7221 guanosine ribonucleotides de novo biosynthesis BM590_B0356 PWY-5482 pyruvate fermentation to acetate II BM590_B0356 PWY-5485 pyruvate fermentation to acetate IV BM590_B0356 PWY-5497 purine nucleobases degradation II (anaerobic) BM590_B0366 PWY-6163 chorismate biosynthesis from 3-dehydroquinate BM590_B0367 PWY-3722 glycine betaine biosynthesis II (Gram-positive bacteria) BM590_B0367 PWY-7494 choline degradation IV BM590_B0375 PWY-2941 L-lysine biosynthesis II BM590_B0375 PWY-2942 L-lysine biosynthesis III BM590_B0375 PWY-5097 L-lysine biosynthesis VI BM590_B0390 PWY-5738 GDP-6-deoxy-D-talose biosynthesis BM590_B0390 PWY-5739 GDP-D-perosamine biosynthesis BM590_B0390 PWY-5740 GDP-L-colitose biosynthesis BM590_B0390 PWY-66 GDP-L-fucose biosynthesis I (from GDP-D-mannose) BM590_B0400 PWY-5265 peptidoglycan biosynthesis II (staphylococci) BM590_B0400 PWY-6470 peptidoglycan biosynthesis V (β-lactam resistance) BM590_B0400 PWY-6471 peptidoglycan biosynthesis IV (Enterococcus faecium) BM590_B0417 PWY-4261 glycerol degradation I BM590_B0464 PWY-4381 fatty acid biosynthesis initiation I BM590_B0466 PWY-7380 biotin biosynthesis from 8-amino-7-oxononanoate II BM590_B0468 PWY-7380 biotin biosynthesis from 8-amino-7-oxononanoate II BM590_B0486 PWY-7545 pyruvate to cytochrome bd terminal oxidase electron transfer BM590_B0496 PWY-5046 2-oxoisovalerate decarboxylation to isobutanoyl-CoA BM590_B0499 PWY-5046 2-oxoisovalerate decarboxylation to isobutanoyl-CoA BM590_B0499 PWY-5084 2-oxoglutarate decarboxylation to succinyl-CoA BM590_B0502 PWY-5154 L-arginine biosynthesis III (via N-acetyl-L-citrulline) BM590_B0512 PWY-3821 galactose degradation III BM590_B0512 PWY-6317 galactose degradation I (Leloir pathway) BM590_B0512 PWY-6397 mycolyl-arabinogalactan-peptidoglycan complex biosynthesis BM590_B0512 PWY-6527 stachyose degradation BM590_B0512 PWY-7328 superpathway of UDP-glucose-derived O-antigen building blocks biosynthesis BM590_B0512 PWY-7344 UDP-D-galactose biosynthesis BM590_B0514 PWY-5129 sphingolipid biosynthesis (plants) BM590_B0515 PWY-7346 UDP-α-D-glucuronate biosynthesis (from UDP-glucose) BM590_B0517 PWY-7456 mannan degradation BM590_B0544 PWY-6826 phosphatidylcholine biosynthesis VI BM590_B0554 PWY-6749 CMP-legionaminate biosynthesis I BM590_B0555 PWY-5514 UDP-N-acetyl-D-galactosamine biosynthesis II BM590_B0561 PWY-6987 lipoate biosynthesis and incorporation III (Bacillus) BM590_B0561 PWY-7381 lipoate biosynthesis and incorporation (glycine cleavage system, yeast) BM590_B0565 PWY-5921 glutaminyl-tRNAgln biosynthesis via transamidation BM590_B0571 PWY-5686 UMP biosynthesis BM590_B0572 PWY-5686 UMP biosynthesis BM590_B0604 PWY-1361 benzoyl-CoA degradation I (aerobic) BM590_B0604 PWY-2361 3-oxoadipate degradation BM590_B0604 PWY-6185 4-methylcatechol degradation (ortho cleavage) BM590_B0610 PWY-6215 4-chlorobenzoate degradation BM590_B0612 PWY-6185 4-methylcatechol degradation (ortho cleavage) BM590_B0622 PWY-6610 adenine and adenosine salvage IV BM590_B0623 PWY-7533 gliotoxin biosynthesis BM590_B0658 PWY-6167 flavin biosynthesis II (archaea) BM590_B0658 PWY-6168 flavin biosynthesis III (fungi) BM590_B0670 PWY-6854 ethylene biosynthesis III (microbes) BM590_B0684 PWY-6507 4-deoxy-L-threo-hex-4-enopyranuronate degradation BM590_B0689 PWY-5737 (5R)-carbapenem carboxylate biosynthesis BM590_B0689 PWY-6853 ethylene biosynthesis II (microbes) BM590_B0689 PWY-6922 L-Nδ-acetylornithine biosynthesis BM590_B0698 PWY-381 nitrate reduction II (assimilatory) BM590_B0698 PWY-5675 nitrate reduction V (assimilatory) BM590_B0698 PWY-6549 L-glutamine biosynthesis III BM590_B0698 PWY-6963 ammonia assimilation cycle I BM590_B0698 PWY-6964 ammonia assimilation cycle II BM590_B0707 PWY-7383 anaerobic energy metabolism (invertebrates, cytosol) BM590_B0725 PWY-6840 homoglutathione biosynthesis BM590_B0725 PWY-7255 ergothioneine biosynthesis I (bacteria) BM590_B0731 PWY-381 nitrate reduction II (assimilatory) BM590_B0731 PWY-5675 nitrate reduction V (assimilatory) BM590_B0731 PWY-6549 L-glutamine biosynthesis III BM590_B0731 PWY-6963 ammonia assimilation cycle I BM590_B0731 PWY-6964 ammonia assimilation cycle II BM590_B0741 PWY-7268 NAD/NADP-NADH/NADPH cytosolic interconversion (yeast) BM590_B0742 PWY-5514 UDP-N-acetyl-D-galactosamine biosynthesis II BM590_B0742 PWY-6855 chitin degradation I (archaea) BM590_B0742 PWY-6906 chitin derivatives degradation BM590_B0743 PWY-5101 L-isoleucine biosynthesis II BM590_B0743 PWY-5103 L-isoleucine biosynthesis III BM590_B0743 PWY-5104 L-isoleucine biosynthesis IV BM590_B0743 PWY-7111 pyruvate fermentation to isobutanol (engineered) BM590_B0744 PWY-1722 formate reduction to 5,10-methylenetetrahydrofolate BM590_B0744 PWY-2201 folate transformations I BM590_B0744 PWY-3841 folate transformations II BM590_B0744 PWY-5030 L-histidine degradation III BM590_B0744 PWY-5497 purine nucleobases degradation II (anaerobic) BM590_B0744 PWY-6613 tetrahydrofolate salvage from 5,10-methenyltetrahydrofolate BM590_B0745 PWY-3341 L-proline biosynthesis III BM590_B0745 PWY-4981 L-proline biosynthesis II (from arginine) BM590_B0745 PWY-6344 L-ornithine degradation II (Stickland reaction) BM590_B0754 PWY-241 C4 photosynthetic carbon assimilation cycle, NADP-ME type BM590_B0754 PWY-6142 gluconeogenesis II (Methanobacterium thermoautotrophicum) BM590_B0754 PWY-7115 C4 photosynthetic carbon assimilation cycle, NAD-ME type BM590_B0754 PWY-7117 C4 photosynthetic carbon assimilation cycle, PEPCK type BM590_B0756 PWY-5188 tetrapyrrole biosynthesis I (from glutamate) BM590_B0759 PWY-1361 benzoyl-CoA degradation I (aerobic) BM590_B0759 PWY-5109 2-methylbutanoate biosynthesis BM590_B0759 PWY-5136 fatty acid β-oxidation II (peroxisome) BM590_B0759 PWY-5138 unsaturated, even numbered fatty acid β-oxidation BM590_B0759 PWY-5177 glutaryl-CoA degradation BM590_B0759 PWY-5789 3-hydroxypropanoate/4-hydroxybutanate cycle BM590_B0759 PWY-6435 4-hydroxybenzoate biosynthesis V BM590_B0759 PWY-6583 pyruvate fermentation to butanol I BM590_B0759 PWY-6863 pyruvate fermentation to hexanol BM590_B0759 PWY-6883 pyruvate fermentation to butanol II BM590_B0759 PWY-6944 androstenedione degradation BM590_B0759 PWY-6945 cholesterol degradation to androstenedione I (cholesterol oxidase) BM590_B0759 PWY-6946 cholesterol degradation to androstenedione II (cholesterol dehydrogenase) BM590_B0759 PWY-7007 methyl ketone biosynthesis BM590_B0759 PWY-7046 4-coumarate degradation (anaerobic) BM590_B0759 PWY-7094 fatty acid salvage BM590_B0759 PWY-7216 (R)- and (S)-3-hydroxybutanoate biosynthesis BM590_B0759 PWY-735 jasmonic acid biosynthesis BM590_B0759 PWY-7401 crotonate fermentation (to acetate and cyclohexane carboxylate) BM590_B0779 PWY-7247 β-D-glucuronide and D-glucuronate degradation BM590_B0779 PWY-7248 pectin degradation III BM590_B0780 PWY-7247 β-D-glucuronide and D-glucuronate degradation BM590_B0780 PWY-7248 pectin degradation III BM590_B0782 PWY-7242 D-fructuronate degradation BM590_B0797 PWY-723 alkylnitronates degradation BM590_B0818 PWY-6386 UDP-N-acetylmuramoyl-pentapeptide biosynthesis II (lysine-containing) BM590_B0818 PWY-6387 UDP-N-acetylmuramoyl-pentapeptide biosynthesis I (meso-diaminopimelate containing) BM590_B0827 PWY-4261 glycerol degradation I BM590_B0828 PWY-4261 glycerol degradation I BM590_B0828 PWY-6118 glycerol-3-phosphate shuttle BM590_B0828 PWY-6952 glycerophosphodiester degradation BM590_B0833 PWY-1042 glycolysis IV (plant cytosol) BM590_B0833 PWY-5484 glycolysis II (from fructose 6-phosphate) BM590_B0833 PWY-6142 gluconeogenesis II (Methanobacterium thermoautotrophicum) BM590_B0833 PWY-7003 glycerol degradation to butanol BM590_B0835 PWY-1042 glycolysis IV (plant cytosol) BM590_B0835 PWY-1861 formaldehyde assimilation II (RuMP Cycle) BM590_B0835 PWY-5484 glycolysis II (from fructose 6-phosphate) BM590_B0835 PWY-6142 gluconeogenesis II (Methanobacterium thermoautotrophicum) BM590_B0835 PWY-7385 1,3-propanediol biosynthesis (engineered) BM590_B0836 PWY-5484 glycolysis II (from fructose 6-phosphate) BM590_B0849 PWY-2941 L-lysine biosynthesis II BM590_B0849 PWY-2942 L-lysine biosynthesis III BM590_B0849 PWY-5097 L-lysine biosynthesis VI BM590_B0849 PWY-5154 L-arginine biosynthesis III (via N-acetyl-L-citrulline) BM590_B0849 PWY-6559 spermidine biosynthesis II BM590_B0849 PWY-6562 norspermidine biosynthesis BM590_B0849 PWY-7153 grixazone biosynthesis BM590_B0849 PWY-7400 L-arginine biosynthesis IV (archaebacteria) BM590_B0853 PWY-7396 butanol and isobutanol biosynthesis (engineered) BM590_B0863 PWY-31 canavanine degradation BM590_B0863 PWY-4984 urea cycle BM590_B0863 PWY-6305 putrescine biosynthesis IV BM590_B0863 PWY-6922 L-Nδ-acetylornithine biosynthesis BM590_B0873 PWY-2201 folate transformations I BM590_B0873 PWY-5497 purine nucleobases degradation II (anaerobic) BM590_B0875 PWY-6906 chitin derivatives degradation BM590_B0875 PWY-7077 N-acetyl-D-galactosamine degradation BM590_B0875 PWY-7395 D-galactosamine and N-acetyl-D-galactosamine degradation BM590_B0887 PWY-7383 anaerobic energy metabolism (invertebrates, cytosol) BM590_B0895 PWY-5028 L-histidine degradation II BM590_B0895 PWY-5030 L-histidine degradation III BM590_B0899 PWY-5028 L-histidine degradation II BM590_B0899 PWY-5030 L-histidine degradation III BM590_B0907 PWY-2221 Entner-Doudoroff pathway III (semi-phosphorylative) BM590_B0907 PWY-6507 4-deoxy-L-threo-hex-4-enopyranuronate degradation BM590_B0907 PWY-7242 D-fructuronate degradation BM590_B0907 PWY-7310 D-glucosaminate degradation BM590_B0908 PWY-7130 L-glucose degradation BM590_B0909 PWY-5101 L-isoleucine biosynthesis II BM590_B0909 PWY-5103 L-isoleucine biosynthesis III BM590_B0909 PWY-5104 L-isoleucine biosynthesis IV BM590_B0909 PWY-7111 pyruvate fermentation to isobutanol (engineered) BM590_B0930 PWY-3722 glycine betaine biosynthesis II (Gram-positive bacteria) BM590_B0930 PWY-7494 choline degradation IV BM590_B0947 PWY-3781 aerobic respiration I (cytochrome c) BM590_B0947 PWY-4521 arsenite oxidation I (respiratory) BM590_B0947 PWY-6692 Fe(II) oxidation BM590_B0947 PWY-7279 aerobic respiration II (cytochrome c) (yeast) BM590_B0960 PWY-6167 flavin biosynthesis II (archaea) BM590_B0983 PWY-5921 glutaminyl-tRNAgln biosynthesis via transamidation BM590_B1001 PWY-5154 L-arginine biosynthesis III (via N-acetyl-L-citrulline) BM590_B1001 PWY-7400 L-arginine biosynthesis IV (archaebacteria) BM590_B1023 PWY-2723 trehalose degradation V BM590_B1023 PWY-5514 UDP-N-acetyl-D-galactosamine biosynthesis II BM590_B1023 PWY-5661 GDP-glucose biosynthesis BM590_B1023 PWY-7238 sucrose biosynthesis II BM590_B1023 PWY-7385 1,3-propanediol biosynthesis (engineered) BM590_B1025 PWY-2941 L-lysine biosynthesis II BM590_B1025 PWY-2942 L-lysine biosynthesis III BM590_B1025 PWY-5097 L-lysine biosynthesis VI BM590_B1026 PWY-1622 formaldehyde assimilation I (serine pathway) BM590_B1026 PWY-5484 glycolysis II (from fructose 6-phosphate) BM590_B1028 PWY-5508 adenosylcobalamin biosynthesis from cobyrinate a,c-diamide II BM590_B1028 PWY-5523 5,6-dimethylbenzimidazole biosynthesis BM590_B1040 PWY-5839 menaquinol-7 biosynthesis BM590_B1040 PWY-5844 menaquinol-9 biosynthesis BM590_B1040 PWY-5849 menaquinol-6 biosynthesis BM590_B1040 PWY-5890 menaquinol-10 biosynthesis BM590_B1040 PWY-5891 menaquinol-11 biosynthesis BM590_B1040 PWY-5892 menaquinol-12 biosynthesis BM590_B1040 PWY-5895 menaquinol-13 biosynthesis BM590_B1042 PWY-7183 pyrimidine nucleobases salvage I BM590_B1048 PWY-6454 vancomycin resistance I BM590_B1048 PWY-6901 superpathway of glucose and xylose degradation BM590_B1059 PWY-5921 glutaminyl-tRNAgln biosynthesis via transamidation BM590_B1078 PWY-1361 benzoyl-CoA degradation I (aerobic) BM590_B1078 PWY-5109 2-methylbutanoate biosynthesis BM590_B1078 PWY-5136 fatty acid β-oxidation II (peroxisome) BM590_B1078 PWY-5138 unsaturated, even numbered fatty acid β-oxidation BM590_B1078 PWY-5177 glutaryl-CoA degradation BM590_B1078 PWY-5789 3-hydroxypropanoate/4-hydroxybutanate cycle BM590_B1078 PWY-6435 4-hydroxybenzoate biosynthesis V BM590_B1078 PWY-6583 pyruvate fermentation to butanol I BM590_B1078 PWY-6863 pyruvate fermentation to hexanol BM590_B1078 PWY-6883 pyruvate fermentation to butanol II BM590_B1078 PWY-6944 androstenedione degradation BM590_B1078 PWY-6945 cholesterol degradation to androstenedione I (cholesterol oxidase) BM590_B1078 PWY-6946 cholesterol degradation to androstenedione II (cholesterol dehydrogenase) BM590_B1078 PWY-7007 methyl ketone biosynthesis BM590_B1078 PWY-7046 4-coumarate degradation (anaerobic) BM590_B1078 PWY-7094 fatty acid salvage BM590_B1078 PWY-7216 (R)- and (S)-3-hydroxybutanoate biosynthesis BM590_B1078 PWY-735 jasmonic acid biosynthesis BM590_B1078 PWY-7401 crotonate fermentation (to acetate and cyclohexane carboxylate) BM590_B1139 PWY-5386 methylglyoxal degradation I